Conformal Ionic Mixtures
نویسندگان
چکیده
منابع مشابه
Triphilic Ionic-Liquid Mixtures: Fluorinated and Non-fluorinated Aprotic Ionic-Liquid Mixtures
We present here the possibility of forming triphilic mixtures from alkyl- and fluoroalkylimidazolium ionic liquids, thus, macroscopically homogeneous mixtures for which instead of the often observed two domains-polar and nonpolar-three stable microphases are present: polar, lipophilic, and fluorous ones. The fluorinated side chains of the cations indeed self-associate and form domains that are ...
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The structures of mixtures of ionic liquids (ILs) featuring a common 1-butyl-3-methylimidazolium ([C4C1im](+)) cation but different anions have been investigated both experimentally and computationally. (1)H and (13)C NMR of the ILs and their mixtures has been performed both on the undiluted liquids and those diluted by CD2Cl2. These experiments have been complemented by quantum chemical densit...
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Ionic liquids have earned the reputation of being 'designer solvents' due to the wide range of accessible properties and the degree of fine-tuning afforded by varying the constituent ions. Mixtures of ionic liquids offer the opportunity for further fine-tuning of properties. A broad selection of common ionic liquid cations and anions are employed to create a sample of binary and reciprocal bina...
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The phase separation of ionic liquids (ILs) in water is studied by laser light scattering (LLS). For the ILs with longer alkyl chains, such as [C(8)mim]BF(4) and [C(6)mim]BF(4) (mim = methylimidazolium), macroscopic phase separation occurs in the mixture with water. LLS also reveals the coexistence of the mesoscopic phase, the size of which is in the order of 100-800 nm. In aqueous mixtures of ...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1963
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.1734071